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Q.

The incorrect statement about aniline is

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a

 it is less basic than ethyl amine

b

 it is steam volatile

c

on reaction with Na, it gives H2

d

 it is highly soluble in water

answer is D.

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Detailed Solution

  •  Aniline is immiscible with water. It is soluble in organic solvents such as ether, alcohol, benzene, etc. Thus, it is incorrect to say that aniline is highly soluble in water. Rest all of the given statements are correct. Aniline is steam volatile, it is less basic than ethyl amine, and on reaction with Na, it gives H2.

Hence, the correct answer is option D) it is highly soluble in water.

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