Q.

The incorrect statement(s) regarding diborane B2H6 is/are : 

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a

Maximum six atoms can lie in a plane.

b

 Terminal Ht-B^-Ht bond angle is greater than bridging Hb-B^-Hb bondangle 

c

Maximum six hydrogen atoms can lie in a plane

d

 Bridging Hb-B-Hb bond is stronger than terminal B-Ht bond 

answer is A.

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Detailed Solution

Question Image

(a) Maximum 4-H -atom can lie in a plane.

(b) Maximum 6-atom can lie in a plane (H,,H1,B,Ht,Ht,B) 

(c) Bond strength (B Hb - - -B) > (B - H,)
(d) (H, -B -Ht) > (Hu ---B ---Hu) 

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