Q.

The increase of pressure on  ice  water system at constant temperature will lead to

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a

an increase in Gibbs energy of the system

b

a decrease in the entropy of the system

c

a shift of the equilibrium in the forward direction

d

no effect on the equilibrium

answer is C.

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Detailed Solution

Increase in pressure shifts the equilibrium towards the lesser volume side. Since the molar volume of liquid water is smaller than that of ice, equilibrium will shift in the forward direction.

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The increase of pressure on  ice ⇌ water system at constant temperature will lead to