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The increasing order of nucleophilicity of the following nucleophiles is:
i) CH₃CO $\bar{O}$ ii) H₂O iii) CH₃S $\bar{O}$ ₃ iv) O $\bar{H}$

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ii>iii>i>iv

ii<iii<i<iv

i<iv<iii<ii

ii<i<iii<iv

answer is A.

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Detailed Solution

For the same atom(0), nucleophilicity will follow the order of basicity :
$H_{2} O < {CH}_{3} S {\overset{⊖}{O}}_{3} < {CH}_{3} CO \overset{⊖}{O} < \overset{⊖}{H}$

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