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Q.

The increasing order of the rate of HCN addition to compound A — D is 
(A) HCHO  (B) CH3COCH (C) PhCOCH (D) PhCOPh 

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a

A<B<C<D

b

C<D<B<A

c

D<B<C<A

d

D<C<B<A

answer is A.

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Detailed Solution

Addition of HCN to carbonyl compounds is nucleophilic addition reaction. The order of reactivity of carbonyl compounds is Aldehydes (smaller to higher) Ketones (smaller to higher), Then 
PhCOPh<Ph.COCH3<CH3COCH3<HCHO
The lower reactivity of ketones is due to presence of two alkyl group which shows +I effect. The reactivity of ketones decreases as the size of alkyl group increases. 

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