Q.

The increasing order of the rate of HCN addition to compounds

(A) HCHO

(B) CH3COCH3

(C) PhCOCH3and 

(D) PhCOPh is 

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a

C < D < B < A

b

A < B < C < D

c

D < B < C < A

d

D < C < B < A

answer is D.

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Detailed Solution

Increase in crowding at the transition state decreases the rate of addition of HCN. 

The increasing order of the rate of HCN addition to compounds D < C < B < A.

 

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