Q.

The increasing order of the reactivity of the following halides towards SN1 reaction is 

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a

III < II < I

b

II < III < I

c

 II < I < III

d

 I < II < III

answer is C.

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Detailed Solution

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Order of reactivity for SN1 reaction is in accordance to the order of stability of carbocation involved

I produce 20 carbocation

II produce 10 carbocation

III produce P- methoxy benzylic cation 

The order of stability of carbocations formed is 10< 20<P- methoxy benzylic cation 

Therefore  the order of stability is   II < I < III

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