Q.

The indicator constant for an acidic indicator, HIn is  5×10-6M. The indicator appears only in the colour of acidic form when [InHIn]120  and it appears only in the colour of basic form when [HInIn]140 . The pH range of indicator is [Given: log 5 = 0.7]

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a

4.0 – 6.9

b

4.3 – 6.3

c

3.7 – 6.6

d

6.0 – 6.9

answer is B.

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Detailed Solution

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pkxn=5×106;HInH++In KIN=[H+][In][HIn] [H+]=KIn[HIn][In];pH=pkIn+log[In][HIn] pH=6log5+log120=60.71.3=62=4.0 pH=6log5+log40=60.7+1.6=6.9

 Range in 4.0 to 6.9

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