Q.

The initial concentration of N2O5 in the following first order reaction:

N2O5(g)2NO2(g)+12O2(g) was 1.24×102 mol/L at 318 K. The concentration of N2O5 after 60 minutes was 0.20×102 mol/L. The rate constant of the reaction in min1 is  x×102, value of x is log 6.2=0.792.

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answer is 3.

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Detailed Solution

K=2.303t2t1logR1R2=2.30360log1.24×1020.2×102=2.30360log6.2

0.0304=3×102
[ ref : NCERT solved example 4.5]

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