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Q.

The initial rate of hydrolysis of methyl acetate (1M) by a weak acid (HA, 1M) is 1/100th of that of a strong acid (HX, 1M), at 25C. The Ka of HA is

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a

1×104

b

1×105

c

1×106

d

1×103

answer is A.

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Detailed Solution

r=K[CH3COOCH3][H2O][H+]

rHArMX=[H+]from HA[H+]from HX

1100=[H+]from HA1[H+] from HA=102M

HA(aq)11021  H+(aq)102+A(aq)102

ka=102×1021=104

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The initial rate of hydrolysis of methyl acetate (1M) by a weak acid (HA, 1M) is 1/100th of that of a strong acid (HX, 1M), at 25∘C. The Ka of HA is