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Q.

The initial rates of reaction 3A+2B+CProducts, at different initial concentrations are given below:
 

Initial rate Ms-1[A]0,M[B]0,M[C]0,M
5.0 x 10-3 0.0100.0050.010
5.0 x 10-30.010 0.0050.015
1.0 x 10-2 0.010 0.010 0.010 
1.25 x 10-3 0,005 0,005 0.010 

The order with respect to the reactants, A, B and C are respectively 

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a

3,2,1 

b

2,1,0

c

3,2,0 

d

2,2,0 

answer is D.

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Detailed Solution

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From 1st  and 2nd sets of data - no change in rate is observed with the change in concentration of ‘C’ So the order with respect to ‘C’ is zero. From 1st and 4st sets of data Dividing eq. (4) by eq. (1) 
1.25×1035.0×103=0.0050.010x  or 0.25=(0.5)x or (0.5)2=(0.5)x x=2  The order with respect to ' A ' is 2 from the 1st  and 3rd  sets of data dividing eq. (1) by eq. (3)  5.0×1031.0×102=0.0050.010y  or (0.5)1=(0.5)yy=1 The order with respect to B is 1 So the order with respective the reactants A, B and C is 2, 1 andO.

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