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Q.

The ion which is not tetrahedral in shape :

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a

BF4

b

NH4+

c

XeO4

d

ICl4

answer is D.

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Detailed Solution

The element ICl4

2 lone pairs of electrons and 4 bond pairs of electrons are present. sp3d2 hybridization occurs on the central iodine atom. The actual geometry is square planar as opposed to the anticipated octahedral shape. 

BF4, NH4+ and XeO4 are shaped like tetrahedrons.

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