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Q.

The ionic conductivity of Ba²⁺ and Cl^- at infinite dilution are 127 and 76 ohm^-1 cm²eq^-1, respectively. The equivalent conductivity of BaCl₂ at infinity dilution (in ohm^-1cm²eq^-1) would be :

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a

101.5

b

203

c

279

d

139.5

answer is D.

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Detailed Solution

$B a C l_{2} \to B a^{2 +} + 2 C l^{-}$
$Λ_{B a C l_{2}}^{\circ} = Λ_{B a^{2 +}}^{\circ} + 2 Λ_{C l^{-}}^{\circ}$
$= 127 + (2 \times 76)$
$= 279 o h m^{- 1} c m^{2} e q^{- 1}$
Equivalent conductivity =279 $= \frac{279}{2}$
=139.5ohm⁻¹cm²eq⁻¹

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