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Q.

The ionisation constant of an acid, Ka is the measure of strength of an acid. The Ka values of acetic acid, hypochlorous acid and formic acid are 1.74 x 10-5, 3.0 x 10- 8 and 1.8 x 10- 4, respectively. Which of the following orders of pH of 0.1 mol dm- 3 solutions of these acids is correct?

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a

Acetic acid > hypochlorous acid > formic acid

b

Hypochlorous acid > acetic acid > formic acid

c

Formic acid > hlpochlorous acid > acetic acid

d

Formic acid > acetic acid > hypochlorous acid

answer is D.

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Detailed Solution

More is the acidic character, more is the value of Ka. High acidic character of acid have low value of pH.

Ka value is smallest for formic acid and highest for hypochlorous acid. Therefore, the correct order of the given acids:

Hypochlorous acid < Acetic acid < Formic acid 

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