Q.

The ionization energies of chlorine and hydrogen are 1256 and 1311 kJ/ mole respectively. Hydrogen forms H(aqueous)  ion, but chlorine does not form Cl+(aqueous) ion, because

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a

 Enthalpy of hydration of H+ is low

b

Electronegativity of  Cl is high

c

 Enthalpy of hydration of  Cl+ is low

d

 Electron affinity of Cl is high

answer is B.

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Detailed Solution

 We know that H2 and Cl2 both are atoms, and the ionization energy of chlorine is 1256 kJ/ mole and of hydrogen is 1311 kJ/ mole. Which is greater than chlorine, but hydrogen is small in size that's why H-H bond breaks easily and the Polar H2O molecule watered into and provides H+(aq), and chlorine is bigger in size that's why its ionization energy is less that's why chlorine does not form Cl+(aqueous) ion.

Hence, option(b) is the answer.

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