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Q.

The ionization energy of  He+ is 19.6×1018Jatom1. Calculate the energy of the first stationary state of  Li2+

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a

19.6×1019Jatom1

b

4.41×1018Jatom1

c

4.41×1017Jatom1

d

19.6×1018Jatom1

answer is D.

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Detailed Solution

I.E of  He+=E×22(asZforHe=2)

I.E. of  Li2+=E×32 (as Z for Li = 3)

Hence,  I.E.(He+)I.E.(Li2+)=49

Therefore, I.E(Li2+)=94×I.E.(He+)

=94×19.6×1018=4.41×1017Jatom1

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The ionization energy of  He+ is 19.6×10−18J atom−1. Calculate the energy of the first stationary state of  Li2+