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Q.

The ionization enthalpy of hydrogen atom is 1.312×106Jmol1.The energy required to excite the electron in the atom from n = 1 to n = 2 is 

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a

9.84×103J  mol1

b

8.51×102J  mol1

c

6.56×105J   mol1

d

7.56×105J  mol1

answer is A.

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Detailed Solution

The energy difference between the two orbits of hydrogen atom is given by

                                                   ΔE=NARhc(1n121n22)

            For ionization n1=1  and  n2=.    Hence,    NARhc=1.312×106mol1

            For n=1n=2,the energy difference is

            ΔE=34(NARhc)=34×1.312×106J  mol1=9.84×105J  mol1

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