The ionization isomer of [Cr(H2O)4Cl(NO2)]Cl is given as

Ionization isomers are the complexes that produces different ions in solution, i.e. they have ions interchanged inside and outside the coordination sphere. [Cr(H2O)4Cl(NO2)]Cl and [Cr(H2O)4Cl2](NO2) have different ions inside and outside the coordinate sphere and they are isomers.Therefore, they are ionization isomers.

The ionization isomer of [Cr(H2O)4Cl(NO2)]Cl is given as

Ionization isomers are the complexes that produces different ions in solution, i.e. they have ions interchanged inside and outside the coordination sphere. [Cr(H2O)4Cl(NO2)]Cl and [Cr(H2O)4Cl2](NO2) have different ions inside and outside the coordinate sphere and they are isomers.Therefore, they are ionization isomers.

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The ionization isomer of [Cr(H₂O)₄Cl(NO₂)]Cl is given as

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[Cr(H₂O)₄Cl₂(NO₂)].H₂O

[Cr(H₂O)₄(O₂N)]Cl₂

[Cr(H₂O)₄Cl₂]NO₂

[Cr(H₂O)₄Cl(ONO)]Cl

answer is B.

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Detailed Solution

Ionization isomers are the complexes that produces different ions in solution, i.e. they have ions interchanged inside and outside the coordination sphere.
[Cr(H₂O)₄Cl(NO₂)]Cl and [Cr(H₂O)₄Cl₂](NO₂) have different ions inside and outside the coordinate sphere and they are isomers.
Therefore, they are ionization isomers.

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