The ionization isomer of [Cr(H2O)4Cl(NO2)]Cl is given as

[Cr(H 2 O) 4 Cl 2 (NO 2 )].H 2 O

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The ionization isomer of [Cr(H₂O)₄Cl(NO₂)]Cl is given as

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[Cr(H₂O)₄(O₂N)]Cl₂

[Cr(H₂O)₄Cl₂]NO₂

[Cr(H₂O)₄Cl(ONO)]Cl

[Cr(H₂O)₄Cl₂(NO₂)].H₂O

answer is B.

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Ionization isomers are the complexes that produces different ions in solution, i.e. they have ions interchanged inside and outside the coordination sphere.
[Cr(H₂O)₄Cl(NO₂)]Cl and [Cr(H₂O)₄Cl₂](NO₂) have different ions inside and outside the coordinate sphere and they are isomers.
Therefore, they are ionization isomers.

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