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Q.

The IUPAC name for the following compounds

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a

2,5- dimethyl -5- carboxy-hex-3- enal

b

2,5-dimethyl-6-carboxy-hex-3-enal

c

2,5- dimethyl – 6 – oxo- hex-3-enoic acid

d

6- formyl-2-methyl-hex-3-enoic acid

answer is C.

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Detailed Solution

The structure in the image contains both an aldehyde (-CHO) and a carboxylic acid (-COOH) functional group, as well as a methyl group and a double bond. Let’s assign IUPAC nomenclature step by step:

Stepwise Solution

  1. Identify the longest carbon chain containing both functional groups:
    • The chain contains 6 carbon atoms.
  2. Assign priority to functional groups:
    • Carboxylic acid gets highest priority, so numbering starts from the -COOH group.
  3. Number the chain:
    • 1: -COOH
    • 2: C with -CH₃ (methyl)
    • 3: double bond location (3-4)
    • 5: -CHO (aldehyde)
  4. Substituents:
    • Methyl at position 2.
    • Aldehyde (oxo group) at position 5.
    • Double bond between positions 3 and 4.
  5. Final name format:
    • 5-Formyl-2-methylhex-3-enoic acid (where formyl is the prefix for the –CHO when a higher-priority group is present)

IUPAC Name

The IUPAC name for the compound in the image is: 5-Formyl-2-methylhex-3-enoic acid.

If you need this explanation in HTML, let me know.The given structure is a six-carbon chain with a carboxylic acid (-COOH) at one end, an aldehyde (-CHO) group at the fifth carbon, a double bond between carbons 3 and 4, and a methyl group at carbon 2.

Stepwise Solution

  • Longest chain: 6 carbons (hexanoic acid backbone)
  • Principal group: Carboxylic acid (so, numbering starts from the –COOH end)
  • Substituents:
    • Methyl group at carbon-2
    • Aldehyde (as a formyl/oxo substituent) at carbon-5
    • Double bond between C-3 and C-4

IUPAC Name

The IUPAC name is 5-formyl-2-methylhex-3-enoic acid.

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