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Q.

The IUPAC name of the complex PtNH32Cl2 is

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a

diammine dichlorido platinum (II)

b

bis (ammino) dichloro platinum (IV)

c

platinum (II) diammino dichloride

d

dichloro diammine platinum (II)

answer is B.

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Detailed Solution

  • The ligands are ammonia (NH3), and chloride. 
  • Here, ammonia is neutral ligand. 
  • So, it will be written as ammine, whereas chloride is an anion, so it will be written as chloride (ide to –o).
  • In this complex, there are two ammine ligands, so the greek prefix di- will be added before the ammine while naming the complex i.e. diammine.
  • Now, the central metal present in the complex is a cation, it is named the same as the element i.e. platinum.
  • We will calculate the oxidation state of platinum in the complex. 
  • we know that charge of ammine ligand is 0, and the chlorine has -1 charge.
  • So, let us consider the oxidation state of platinum to be x.
  • The oxidation state can be written as: x + 2 (0) + 2(-1) = 0;
  • Here, we get x = 2, as the complex is neutral as mentioned.
  • Thus, in this complex we have the oxidation state of platinum is +2.
  • Now, we will write alphabetically, then it will be diamminedichloridoplatinum (II).
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