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Q.

The IUPAC name of the compound BrClCH.CF3 is

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a

1-bromo-1-chloro-2, 2, 2- trifloroethane

b

haloethane

c

1, 1, 1- trifluoro-2-bromo-2-chloroethane

d

2-bromo-2-chloro-1, 1, 1- trifluoroethane

answer is D.

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Detailed Solution

Answer: 1,1,1-trifluoro-2-bromo-2-chloropropane.

The IUPAC name explained

The compound shown has a central carbon bonded to four groups: Br, Cl, CH3, and CF3. This makes a three-carbon chain overall: CH3–C(Br)(Cl)–CF3. The longest carbon chain contains three carbons, so the parent hydrocarbon is propane. Both halogens (bromo and chloro) sit on the middle carbon (carbon-2). The terminal carbon on one end is a trifluoromethyl group, which in IUPAC is named as the parent substituent “1,1,1-trifluoro” on carbon-1 of propane. Putting all parts together in correct order and with lowest locants gives 1,1,1-trifluoro-2-bromo-2-chloropropane.

How to name it step by step (IUPAC rules)

  1. Select the parent chain: Longest continuous chain is three carbons → propane.
  2. Number the chain: Start from the end nearest the first point of difference. The CF3 end gives the lowest set of locants for all substituents.
  3. Identify and locate substituents:
    • Three fluorines on carbon-1 → 1,1,1-trifluoro.
    • Bromine on carbon-2 → 2-bromo.
    • Chlorine on carbon-2 → 2-chloro.
  4. Assemble the name: List substituents alphabetically then parent: 1,1,1-trifluoro-2-bromo-2-chloropropane.

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