Q.

The key step in the manufacturing of H2SO4 by contact process is

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a

Catalytic oxidation of SO2 with O2 to give SO3

b

Buring of sulphur in air to generate SO2

c

Absorption of SO3 in H2SO4 to give oleum

d

Dilution of oleum with water

answer is D.

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Detailed Solution

Production of sulphur trioxide from sulphur dioxide in presence of vanadium oxide is a key process in contact process since as much sulphur trioxide is produced more will be absorbed and hence more sulphuric acid will be produced. The reaction that takes place in presence of a catalyst is as follows. 

2SO2( g)+O2( g)V2O5 or Pt 450°C,2 atm.¯2SO3( g);ΔH=-197kJ.mol-1

this sulphur trioxide is the deciding factor for the yield of sulphuric acid more the sulphur trioxide is produced more will be the absorption and more sulphuric acid production thus formation of sulphur trioxide from sulphur dioxide turns out to be the key step.

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