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Q.

The lanthanide contraction is responsible for the fact that:

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a

Zr and Hf have same atomic sizes

b

Zr and Hf have similar properties

c

Zr and Hf have different atomic sizes

d

Zr and Hf have different properties

answer is A.

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Detailed Solution

Group 4 contains both Zr and Hf (d-block). Zr atomic radius (160 pm) is relatively close to Hf (159 pm).
The lanthanide contraction causes Zr and Hf to have comparable characteristics. With an increase in atomic number and effective nuclear charge, the size of Hf and Zr becomes virtually identical, and as a result, both have similar properties. This is because the electrons in the f-subshell do not have a good shielding effect.

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The lanthanide contraction is responsible for the fact that: