Q.

The latent heat of vaporization of water is 9700cal/mole and if the b.p. is 100°C, the ebullioscopic constant of water is

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a

1.832°

b

1.026°

c

0.516°

d

10.26°

answer is A.

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Detailed Solution

The equiliscopic constant is given by-

Kb=RT21000×Lv

Here,


R = Gas constant
T = Boiling point of water on water scale =100+273=373 K
Lv = Latent heat of vapourisation (in cal /gm) = 970018cal/gm

therefore Kb=2×(373)2×181000×9700

Kb=0.516
 

Therefore, Option A is the correct answer

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