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Q.

The Lewis acid nature of BX3 follows the order :

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a

BCl3>BF3>BBr3>BI3

b

BF3>BCl3>BBr3>BI3

c

BF3<BBr3<BCl3<BI3

d

BF3<BCl3<BBr3<BI3

answer is B.

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Detailed Solution

The correct progression of these halides' Lewis-acid strengths is BF3<BCl3<BBr3<BI3. This can be explained by the halogen atom's propensity to donate its single electron pair to the vacant  through p-orbital of the B atom  . bonding. Due to the equal size of the two p-orbitals in B and F, this tendency is stronger in F, which causes a decrease in B's electron shortage and the formation of BF3 acts like the weakest Lewis acid. The likelihood for reverse donation reduces as the size of the halogen atom increases from Cl to I, which causes the electron shortage of B to increase and the Lewis acid character to increase as a result.

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