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Q.

The limiting equivalent conductance of NaCl, KCl and KBr are 126.5,150.0 and 152.0   S  cm2 eq-1respectively. The limiting equivalent ionic conductance of Br  is 76Scm2eq1 . The limiting equivalent ionic conductance of Na+  is  
 

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a

25.5

b

52.5

c

75.5

d

57.5

answer is B.

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Detailed Solution

NaCl=λNa+0+λCl0=126.5           .....(i)

KCl=λK+0+λCl0=150           .....(ii)

KBr=λK+0+λBr0=152           .....(iii)

Adding (i) & (iii)  subtract (ii)

λNa0+λCl0+λK+0+λBr0   λK+0  λCl0=λNa+0+λBr0

=(126.5+152150)=(76)+λNa+0
λNa+0=52.5
 Equivalent ionic conductance for Na+   is  52.5.
 

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