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Q.

The limiting radius ratio of the square planar complex [Ni(CN)4]2– is

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a

0.225 – 0.414 

b

0.414 – 0.732
 

c

0.155 – 0.225 

d

None

answer is B.

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Detailed Solution

The complex [Ni(CN)4]–2 is square planar and its crystals have octahedral structure.  So, it has limiting radius ratio corresponds to octahedral structure, 0.414 – 0.732.

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The limiting radius ratio of the square planar complex [Ni(CN)4]2– is