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Q.

The magnetic moment (BM) of the complexes ${[Ni {(H_{2} O)}_{6}]}^{2 +} and {[Ni {({NH}_{3})}_{6}]}^{2 +}$ are respectively

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a

0, 2.84

b

2.84, 2.84

c

2.84,0

d

1.73, 2.84

answer is D.

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Detailed Solution

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${Ni}^{2 +} : 3 d^{8} {sp}^{3} d^{2}$ (Weakfield or strong field ligand) $μ = 2.84$

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The magnetic moment (BM) of the complexes NiH2O62+ and NiNH362+ are respectively