The magnetic moment (nearest to integer) of the complex [Fe(H₂O)₆][Fe(CN)₆] in which iron atoms in both cation and anion is in same oxidation state

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answer is A.

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Detailed Solution

The complex contain [Fe(H₂O)₆]³⁺ and [Fe(CN)₆]^3– ions. [Fe(H₂O)₆]^3– contains 5 and [Fe(CN)₆]^3– contain one unpaired electrons. Total 6 unpaired electrons so magnetic moment to the nearest integer is 7

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