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Q.

The magnetic moment (spin only) of NiCl42 is

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a

5.46 BM

b

1.41 BM

c

2.82 BM

d

1.85 BM

answer is C.

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Detailed Solution

NiCl42; oxidation number of Ni, x - 4 = -2

x=+2,Ni28Ar3d8,4s2

Question Image

sp3-hybrid orbitals, tetrahedral

Since, Cl- is a weak ligand, thus unpaired electrons are not paired. Lone pairs from 4 Cl- are accommodated in four sp3
hybrid orbitals.
n = unpaired electron = 2, paramagnetic
Magnetic moment (spin only)

=nn+2BM=8=2.828BM

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