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Q.

The magnitudes of enthalpy of combustions of CH4,C2H6,C3H8  and n-butane in kJmol1 are 890, 1560, 2220 & 2879 respectively. The ratio of enthalpies of combustion of n-heptane to that of ethane rounded off to nearest integer is______.

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answer is 3.

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Detailed Solution

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The differencesin enthalpy of combustionsbetween adjacent members given are 670, 660 &659 respectively. i.e, adjacent members differ approximately by about 660.
Magnitude of enthalpy of combustion of n-heptane will be about  2879+3×660=4859
 

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