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Q.

The major product formed when 1, 1, 1 - trichloro - propane is treated with aqueous potassium hydroxide is:

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a

2- Propanol

b

1- Propanol

c

Propyne

d

Propionic acid

answer is D.

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Detailed Solution

Propionic acid is the main byproduct of the treatment of 1, 1, 1-trichloropropane with aqueous potassium hydroxide.
Alc. KOH leads to substitution while aq. KOH causes elimination in the haloalkane molecule generally. Since aq. KOH is being utilised here, a substitution reaction is most advantageous.
The preferred response would be:

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On a carbon atom, there cannot be more than one OH group. A water molecule will be easily lost by the chemical in this scenario, making a more stable aldehyde, ketone, or carboxylic acid.

(HO)3CCH2CH3(HO)COCH2CH3+H2O.

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