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Q.

The major product obtained in the photo catalysed bromination of 2-methylbutane is:

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a

2-bromo-3-methylbutane

b

2-bromo-2-methylbutane

c

l-bromo-2-methylbutane

d

l-bromo-3-methylbutane

answer is D.

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Detailed Solution

Photo catalyzed bromination proceeds through the formation of radicals. Since 3 ° radical is most stable, the product obtained is 2-bromo-2-methyl butane. Bromination in light with tertiary C-H bond 1600 times faster than primary C-H.Question Image

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