The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match List-I with List-II and choose the correct option. List-I List-I I(P)Etard reaction(1)Acetophenone→Zn−Hg,HCl(Q)Gattermann reaction(2)Toulene→iiSOCl2i KMnO4,KOH,Δ(R)Gattermann-Koch reaction(3)Benzene→anhyd.AlCl3CH3Cl(S)Rosenmund reduction(4)Aniline→273−278KNaNO2/HCl 5)Phenol→Zn,Δ (P)(Q)(R)(S)(1)2413(2)1352(3)3214(4)3452

1) 2) Used in Rosenmund reduction ⇒S→23) Used in Etard reaction ⇒P→34) Used in Gattermann reaction ⇒Q→45)⇒R→5

The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match List-I with List-II and choose the correct option. List-I List-I I(P)Etard reaction(1)Acetophenone→Zn−Hg,HCl(Q)Gattermann reaction(2)Toulene→iiSOCl2i KMnO4,KOH,Δ(R)Gattermann-Koch reaction(3)Benzene→anhyd.AlCl3CH3Cl(S)Rosenmund reduction(4)Aniline→273−278KNaNO2/HCl 5)Phenol→Zn,Δ (P)(Q)(R)(S)(1)2413(2)1352(3)3214(4)3452

1) 2) Used in Rosenmund reduction ⇒S→23) Used in Etard reaction ⇒P→34) Used in Gattermann reaction ⇒Q→45)⇒R→5

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The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match List-I with List-II and choose the correct option.

List-I List-I I
(P) Etard reaction (1) $Acetophenone \overset{Zn - Hg, HCl}{\to}$
(Q) Gattermann reaction (2) $Toulene \to_{(ii) {SOCl}_{2}}^{(i) {KMnO}_{4}, KOH, Δ}$
(R) Gattermann-Koch reaction (3) $Benzene \to_{anhyd . {AlCl}_{3}}^{{CH}_{3} Cl}$
(S) Rosenmund reduction (4) $Aniline \to_{273 - 278 K}^{{NaNO}_{2} / HCl}$
5) $Phenol \overset{Zn, Δ}{\to}$
(P) (Q) (R) (S)
(1) 2 4 1 3
(2) 1 3 5 2
(3) 3 2 1 4
(4) 3 4 5 2

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Detailed Solution

1) Question Image

2) Question Image Used in Rosenmund reduction $\Rightarrow S \to 2$
3) Used in Etard reaction $\Rightarrow P \to 3$
4) Used in Gattermann reaction $\Rightarrow Q \to 4$
5) $\Rightarrow R \to 5$

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