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Q.

The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match List-I with List-II and choose the correct option.

 List-I List-II
I)Etard reactionP)AcetophenoneZnHg/HCl
II)Stephen reactionQ)Toluene(ii)SOCl2(i)KMnO4,KOH,Δ
III)Gattermann-koch reactionR)Benzeneanhy.AlCl3CH3Cl
IV)Rosenmend reactionS)Ethyl  iodide KCN
V) T)PhenolZn,Δ

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a

IR,IIS,IIIT,IVQ

b

IP,IIR,IIIT,IVQ

c

IQ,IIS,IIIP,IVR

d

IR,IIQ,IIIP,IVS

answer is B.

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Detailed Solution

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Etard reaction :Aromatic aldehydes (benzaldehyde and its derivatives) are prepared from aromatic hydrocarbons by Etard .

Stephen reaction : Alkyl nitriles on reduction with stannous chloride and hydrochloric acid in dry ether give corresponding imine hydrochlorides which on acid hydrolysis, give corresponding aldehydes.

Gattermann -koch reaction: Aromatic aldehydes (benzaldehyde and its derivatives) are prepared from aromatic hydrocarbons by Gattermann Koch's.

Rosenmund reduction: is the hydrogenation of an acyl chloride to an aldehyde, in presence of catalyst (Pd supported on barium sulphate). Barium sulphate partially poisons Pd metal and prevents over-reduction

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