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Q.

The manganate and permanganate ions are tetrahedral, due to:

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a

 There is no π bonding

b

 The π bonding involves overlap of p-orbitals of oxygen with p-orbitals of manganese

c

 The π bonding involves overlap of d-orbitals of oxygen with d-orbitals of manganese

d

The  π bonding involves overlap of p-orbitals of oxygen with d-orbitals of manganese

answer is D.

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Detailed Solution

  • The π bonding involves overlap of p-orbitals of oxygen with p-orbitals of manganese.
  • Manganate and permanganate ions are tetrahedral because overlapping of p-orbitals of oxygen with d-orbitals of manganese. Manganate- πbonds are of πd-πp type. 
  • In permanganate ( MnO4-),

                        π- bonds are of - type. 

  • In manganate (MnO4-2)

                  π- bonds are of - type. 

 

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