Q.

The mass of a non – volatile, non – electrolyte solute (molar mass = 50 g mol1 ) needed to be dissolved in 114 g of octane to reduce its vapour pressure to 75% is ?

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a

 150 g

b

37.5 g

c

12.5 g

d

16.66 g

answer is C.

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Detailed Solution

P0PP0=ωmωm+wM, As VP is redued to 75%,

 nsolute is not negligible in denominator

75100=ω50ω50+114114

75100=ω50ω50+1

ω=150g

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The mass of a non – volatile, non – electrolyte solute (molar mass = 50 g mol−1 ) needed to be dissolved in 114 g of octane to reduce its vapour pressure to 75% is ?