Q.

The mass of potassium dichromate crystals required to oxidize  750cm3 of 0.6 M Mohr’s  salt solution is (Given, molar mass: potassium dichromate=294, Mohr’s salt=392)

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a

0.49g 

b

0.45 g

c

2.2g

d

22.05g

answer is C.

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Detailed Solution

Mohr’s salt is  FeSO4.(NH4)2SO4.6H2O
Only oxidisable part is  Fe2+
[Fe2+Fe3++e]×6 
 Cr2O72+14H++6e2Cr3++7H2O
 6Fe2++Cr2O72+14H+6Fe3++2Cr3++7H2O
Millimoles of  Fe2+=750×0.6=450mmol
Moles of  Fe2+=4501000=0.450mol
6 moles of  Fe2+1moleofCr2O72
0.450 mole of   Fe2+0.4506=0.0075  mole of  Cr2O72.
 =0.075×294g=22.05g

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