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Q.

The minimum and maximum values of wavelength in the Lyman series of a H atom are, respectively

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a

364.3nm and 653.4 nm

b

91.2 nmand121.5 nm

c

41.2 nmand102.6 nm

d

9.12 nmand121.5 nm

answer is B.

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Detailed Solution

For hydrogen like species , use the following formula to calculate the wavelength Of radiation of spectral series lines.

1λ=R1n12-1n22

Case 1: Minimum wavelength in the Lyman series:

n1=1 n2=2

Then, 1λ=10968771I2-122

1λ=R1-14=3R4

λ=43R=43×109677cm-1

 λ =1.215×10-5cm(or)121.5nm

1λ=R1n12-1n22

Case 2: Maximum wavelength in the Lyman series:

n1=1 n2=

Then, wavelength of line is

1λ1096771(1)2-1()2

1λ=1096771-0=109677cm-1

λ=1109677cm-1=9.117×10-6 cm

 λ=91.2 nm

Note:1nm=10-7 cm

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