Q.

The minimum kinetic energy of an electron, hydrogen ion, helium ion required for ionization of a hydrogen atom is E1 in case electron is collided with hydrogen atom. It is E2 when hydrogen ion is collided and E3 when helium ion is collided. Then

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a

E1=E2=E3

b

E1>E2>E3

c

E1>E3>E2

d

E1<E2<E3

answer is B.

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Detailed Solution

Assuming that ionization occurs as a result of a completely inelastic collision, we can write

          mv0=m+mHV

where m is the mass of incident particle, mH the mass of hydrogen atom, v0 the initial velocity of incident particle and V the final common velocity of the particle after collision. Prior to collision, the KE of the incident particle was

         E0=mv022

The total kinetic energy after collision

          E=m+mHV22=m2v022m+mH

The decrease in kinetic energy must be equal to ionization energy, so we have

           Ei=E0-E=mHm+mHE0   EiE0=mHm+mH

i.e., the greater the mass m, the smaller the fraction of initial kinetic energy that will be used for ionization. Hence, the correct answer is (B).

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