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Q.

The mixture of salts NaCl,NaBr,NaI on adding cone. H2SO4 and followed by warming gives gases respectively :

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a

HCl,Br2,I2

b

Cl2,Br2,I2

c

HCl,HBr,HI

d

CrO2Cl2,Br2,I2

answer is C.

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Detailed Solution

When conc.H2SO4  is added to a mixture of  NaCl,NaBr,NaI the resulting gases are, respectively,  HCl,Br2 and I2

Strong reducing agents HBr and HI are converted to  Br2 and I2 by H2SO4 respectively.

NaCl+ conc. H2SO4Na2SO4+HCl NaBr+ conc. H2SO4Na2SO4+Br2+H2O+SO2 NaI+ conc. H2SO4Na2SO4+I2+H2O+H2S 

 

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