The mixture that forms maximum boiling azeotrope is

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acetone+carbon disulphide.

water + nitric acid

ethanol + water

heptane + octane

answer is B.

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Detailed Solution

Solution that shows a negative deviation from Raoult’s law from maximum boiling point azeotropes
Example: water + nitric acid
(1) Heptane + octane is an ideal solution.
(3) Ethanol + water shows positive deviation.
(4) Acetone + CS₂ shows positive deviation.

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