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Q.

 The mixture which can act like a basic buffer is 

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a

100 ml of 0.1M HCl + 100 ml  of 0.05M NH4OH

b

100 ml of 0.1M NaOH + 100ml of 0.1M CH3COOH

c

200 ml of 0.1 M NaOH + 100 ml of 0.1M CH3COOH

d

200 ml of 0.05 M  HCl  + 100 ml of 0.2M NH4OH

answer is C.

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Detailed Solution

The mixture of weak base and strong acid can acts as  basic buffer, if number of equivalents of weak base are greater than that of strong acid 

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