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Q.

The molal freezing point constant for water is 1.86 K.kg mole-1. The freezing point of 0.1m NaCl solution is

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a

– 1.86°C

b

– 0.372°C

c

– 0.186°C

d

0.372°C

answer is B.

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Detailed Solution

Tf=Kf×m×i  (i=2 for NaCl Na+ +Cl-)

M =0.1 molal

Kf =1.86 0C/molal

Tf=1.86 ×0.1×2 =0.372 0C

Therefore, now freezing point =0 - 0.372 0C==-0.372 0C

where i is vant hoff constant/factor.

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