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Q.

The molal freezing point constant of water is 1.86C/M. Therefore the freezing point of 0.1 M NaCl solution in water is expected to be

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a

– 1.86°C

b

– 0.186°C

c

+ 0.372°C

d

– 0.372°C

answer is C.

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Detailed Solution

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Tf=Kf ×m×i (i=2 ,for Nacl Na++Cl- i =0.1 molal Kf =1.86C  0/molal

Tf=1.86×2×0.1 Tf =0.372 C  0

Therefore, now freezing point = 0−0.372oC=−0.372oC
where i is vant hoff constant/factor.

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