Q.

The molality of a urea solution in which 0.0100 g of urea, NH22CO  is  added  to  0.3000dm3 of water at STP is

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a

33.3 m

b

5.55  ×  104  m

c

3.33  ×  102  m

d

0.555 m

answer is A.

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Detailed Solution

Molality=moles  of  the  solutemassofthe  solvent  in  kgMolesofureanurea  =  0.0100g60gmol1Mass  of  1000  mL  of  solution  =  volume  ×  density                    =300  mL×  1gmL                     1  dm3  =  1000  mL                      =300  gMassof  solvent=300  g0.0100  g=299.9  g=0.2999  kgMolality=0.010060  ×  0.2999  =  5.55×  104  mol  kg1

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