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Q.

The molar conductance of NaCl, HCl and CH3COONa at infinite dilution are 126.45, 426.16 and 91.0 S cm2 mol-1 respectively. The molar conductance of CH3COOH at infinite dilution is. Choose the right option for your answer

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a

540.48 S cm2 mol-1

b

390.71 S cm2 mol-1

c

698.28 S cm2 mol-1

d

201.28 S cm2 mol-1

answer is C.

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Detailed Solution

λMCH3OOOH=λCH3COOM+λNa+M+λH+M+λCrMλNa+MλCrM=λCH3COONaM+λHClMλNaClM
= 91 + 426.16 - 126.45
= 390.71Scm2mole-1

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