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Q.

The molar conductance's at infinite dilution of BaCl2, NaCl and NaOH are respectively 
280×104,126.5×104,248×104Sm2mol1The molar conductance at infinite dilution for  Ba(OH)2 is

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a

523×104Sm2mol1

b

65×104Sm2mol1

c

52.3×104Sm2mol1

d

5.23×104Sm2mol1

answer is A.

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Detailed Solution

μBaCl2=μBa2++2μC1...(i)μNaC1=μNa++μCl....(ii)μNaOH=μNa++μHO.....(iii)for Ba(OH)2(i)+2( iii )2( ii )μBa(OH)2=280×104+2248×1042126.5×104 =523×104Sm2mol1

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