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Q.

The molar conductivities at infinite dilution of barium chloride, sulphuric acid and hydrochloric acid are 280, 860 and 426 S cm2mol1  respectively. The molar conductivity at infinite dilution of barium sulphate is ____ S cm2mol1. (Round off to the Nearest Integer)

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answer is 288.

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Detailed Solution

ΛmBaCl2=280 S cm2 mol1  (i)ΛmH2SO4=860 S cm2 mol1(ii)ΛmHCl =426 S cm2 mol1(iii)    ΛmBaSO4=?Add equation (i) & (ii) and subtract twice of equation (iii),ΛmBaSO4=Λ Ba2++Λ SO42=ΛmBaCl2+ΛmH2SO42Λ HCl= 280+860(426 x 2)=288 S cm2mol1

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