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Q.

The molar conductivities (λm0) at infinite dilution of KBr, HBr and  KNH2 are 120.5,  420.6 and  90.48 S cm2 mol-1 respectively. Find the value of λm0 for  NH3.

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a

511.0Scm2mol1

b

390.5  Scm2mol1

c

256.2  Scm2mol1

d

240.9  Scm2mol1

answer is B.

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Detailed Solution

λ0(NH3)=λ0(H+)+λ0(NH2)           λm0(NH3)=λ0(NH2)+λ0(H+)+λ0(KBr)λ0(KBr)       λ0(KNH2)+λ0(HBr)λ0(KBr)     =90.48+420.6120.5=390.5  S  cm2mol1

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